A convenient synthesis of 2-substituted 4-amino-5-pyrimidinecarbonitriles

Synthesis of the novel 2-halogenated 4-amino-5-pyrimidinecarbonitriles 3a,b starting from ethoxy-methylenemalononitrile 1 and cyanamide is described. Nucleophilic substitution of the reactive halogen atom leads to the derivatives 5a-g, 6 and 7a-h.     

On dielectrics of polymer electrolytes studied by impedance spectroscopy

We present a phenomenological view on dielectric relaxation in polymer electrolytes in the frequency range where conductivity is independent of frequency. Polymer electrolytes are seen as molecular mixtures of an organic polymer and an inorganic salt. The discussion applies also to ionic liquids. The following is based on systems with poly(ethylene oxide) (PEO) comprising the lithium perchlorate salt (LiClO₄) and also pure low-molecular PEO. In those systems, dipole-dipole interactions form an association/dissociation equilibrium which rules properties of the system in the low-frequency region. It turns out that effective concentration, c _S, of relaxing species provides a suitable variable for discussing electrochemical behavior of the electrolytes. Quantity c _S is proportional to the ratio of DC conductivity and mobility. Polymer salt mixtures form weak electrolytes. However, diffusion coefficient and corresponding molar conductivity display the typical (c _S)^1/2 dependence as well known from strong electrolytes, due to the low effective concentration c _S.     

Towards environmentally friendly, dry deposited, water developable molecular glass photoresists

Photoresists based on molecular glasses are gaining more and more importance as resist material to replace polymer based photoresist. In addition environmental issues have to be considered in the long-term. Therefore the paper describes novel negative photoresists containing a ternary mixture of a glassy low molecular functional polyphenol where the film preparation is possible by solvent-free physical vapor deposition. After UV light exposure and a thermal annealing process to enable acid catalyzed crosslinking between the molecular glass and the crosslinker, the photoresist was developed using only water to give well-defined patterns. In order to experimentally study efficiently the multiple parameters such as composition, exposure dose, and development times combinatorial PVD techniques were utilized.     

Impedance spectra of polymer electrolytes

The authors present a phenomenological view on dielectric relaxation in polymer electrolytes. Polymer electrolytes are seen as molecular mixtures of an organic polymer and an inorganic salt. The following is based on systems with high molar mass poly(ethylene oxide) (PEO) and epoxidized natural rubber with 25 mol% of epoxide content (ENR-25) filled with lithium perchlorate (LiClO₄). Dielectric properties of these systems have been studied as a function of salt content at room temperature. Additionally, properties of neat low molar mass PEO were studied as function of temperature. Relaxation-coined dielectric behavior rules the system with PEO in the frequency that ranged up to 10⁶ Hz. Imaginary parts of impedance, tangent loss, and electric modulus spectra show distribution of relaxation times. Comparison of tangent loss (tan δ) spectra and imaginary part of electric modulus (M″) spectra reveals that localized motion dominates long-range motion of dipoles in the low-frequency range. However, discrepancy between them decreases with growing salt content. Scaling of tan δ spectra demonstrates that distribution of relaxation times does not depend on salt content in the range of low frequencies. The ENR-25 system exhibits solely relaxation like a macroscopic dipole. In conclusion, the system with PEO is characterized by individual relaxation of well-interacting dipoles, whereas the system based on ENR-25 is coined by immobilized dipoles that lead in the state of high-salt content to the relaxation behavior of a macroscopic dipole.     

Micromechanical Approach of Martensitic Transformation Problem in Steels

To determine the mechanical behavior of material involving the martensitic phase transformation (for example, steels like 100Cr6), a representative volume element (RVE) model including phase transformation criterion is desireable at micromechanical approach. A framework combining the Eshelby's inclusion theory as well as continuum mechanics with phase-transformation (PT) critical condition at RVE model is presented briefly. And application of this model to estimate the critical aspect ratio of martensitic plate or lath inside homogeneneous stress field is also included, where the RVE can be under uniaxial tension/compression or pure shear loading case. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)